PROPERTIES
OF SF6 (SULFUR HEXAFLUORIDE) GAS.
Toxicity.-
SF6 is odorless, colorless,tasteless, and nontoxic in its pure state. It can,
however, exclude oxygen and cause suffocation. If the normal oxygen content of
air is reduced from 21 percent to less than 13 percent, suffocation can occur
without warning. Therefore, circuit breaker tanks should be purged out after
opening.
Toxicity of
arc products.- Toxic decomposition products are formed when SF6 gas is
subjected to an electric arc. The decomposition products are metal fluorides
and form a white or tan powder. Toxic gases are also formed which have the
characteristic odor of rotten eggs. Do not breathe the vapors remaining in a
circuit breaker where arcing or corona discharges have occurred in the
gas.Evacuate the faulted SF6 gas from the circuit breaker and flush with fresh
air before working on the circuit breaker.
Physical
properties.- SF6 is one of the heaviest known gases with a density about five
times the density of air under similar conditions. SF6 shows little change in
vapor pressure over a wide temperature range and is a soft gas in that it is
more compressible dynamically than air. The heat transfer coefficient of SF6 is
greater than air and its cooling characteristics by convection are about 1.6
times air.
Dielectric strength.- SF6 has a dielectric strength
about three times that of air at one atmosphere pressure for
a given electrode spacing. The dielectric strength increases with increasing
pressure;and at three atmospheres, the dielectric strength is roughly equivalent
to transformer oil. The heaters for SF6 in circuit breakers are required to
keep the gas fromliquefying
because, as the gas liquifies, the pressure drops, lowering the dielectric
strength. The exact dielectric
strength, as compared to air, varies with electrical configuration, electrode
spacing, and electrode configuration.
Arc
quenching.- SF6 is approximately 100 times more effective than air in quenching
spurious arcing. SF6 also has a high thermal heat capacity that can absorb the
energy of the arc without much of a temperature rise.
Electrical
arc breakdown.- Because of the arc-quenching ability of SF6,corona and arcing
in SF6 does not occur until way past the voltage level of onset of corona and
arcing in air.SF6 will slowly ecompose when exposed to continuous corona.
All SF6 breakdown
or arc products are toxic. Normal circuit breaker operation produces small
quantities of arc products during current interruption which normally recombine
to SF6. Arc products which do not recombine, or which combine with any oxygen
or moisture present, are normally removed by the molecular sieve filter material
within the circuit breaker.
HANDLING
NONFAULTED SF6.
The procedures for handling nonfaulted SF6 are well covered in
manufacturers' instruction books. These procedures normally consist of removing
the SF6 fromthe circuit
breaker, filtering and storing it in a gas cart as a liquid, and transferring
it back to the circuit breaker after the circuit breaker maintenance has been
performed. No special dress or precautions are required when handling
nonfaulted SF6.
HANDLING
FAULTED SF6.-
Toxicity.-
Faulted SF6 gas.- Faulted SF6 gas smells like
rotten eggs and can cause nausea and minor irritation of the eyes and upper respiratory
tract. Normally, faulted SF6 gas is so foul smelling no one can stand exposure
long enough at a concentration high enough to cause permanent damage.
Solid arc
products.- Solid arc products are toxic and are a white or off-white, ashlike
powder. Contact with
the skin may cause an irritation or possible painful fluoride burn. If solid
arc products come in
contact with the skin,wash immediately with a large amount of water. If water
is not available,
vacuum off arc products with a vacuum cleaner.
Clothing and
safety equipment requirements.- When handling and removing solid arc products
from faulted SF6, the following clothing and safety equipment should be worn:
Coveralls.- Coveralls must be worn when removing
solid arc products. Coveralls are not required after all solid arc products are
cleaned up.Disposable coveralls are recommended for use
when removing solid arc products; however,
regular coveralls can be worn if disposable ones are not available, provided
they are washed at the end of each day.
Hoods.-
Hoods must be worn when removing solid arc products from inside a faulted
dead-tank circuit breaker.
Gloves.-
Gloves must be worn when solid arc products are hahdied. Inexpensive,
disposable gloves are recommended. Nondisposable gloves must be washed in water
and allowed to drip-dry after use.
Boots.-
Slip-on boots, nondisposable or plastic disposable,must be worn by employees who
enter eternally faulted dead-tank circuit breakers. Slip-on boots are not
required after the removal of solid arc products and vacuuming. Nondisposable
boots must be washed in water and dried after use.
Safety glasses.- Safety glasses are recommended
when handling solid arc products if a full face respirator is not worn.
Respirator.- A cartridge, dust type respirator is
required when entering an internally faulted dead-tank circuit breaker. The respirator
will remove solid arc products from air breathed, but it does not supply oxygen
so it must only be used when there is sufficient oxygen to support life.
The filter and
cartridge should be changed when an odor is sensed through the respirator. The use of respirators
is optional for work on circuit breakers whose interrupter units are not large enough
for a man to enter and the units are well ventilated.
Air-line-type
respirators should be used when the cartridge type is ineffective due to providing
too short a work
time before the cartridge becomes contaminated and an odor is sensed.
When an air-line
respirator is used, a minimum of two working respirators must be available on the job before
any employee is allowed to enter the circuit breaker tank.
Disposal of waste.-
All materials used in the cleanup operation for large quantities of SF6 arc products
shall be placed in a 55gal drum and disposed of as hazardous waste.
The following
items should be disposed of:
a.All solid
arc products
b.All disposable
protective clothing
c.All cleaning
rags
d.Filters from
respirators
e.Molecular
sieve from breaker and gas cart
f.Vacuum filter
element.